PittsburghV1, Main, Exploration, bibRecord, 000013

Rare Earth pcu Metal–Organic Framework Platform Based on RE 4 (μ 3 -OH) 4 (COO) 6 2+ Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths

Identifieur interne : 000013 ( Main/Exploration ); précédent : 000012; suivant : 000014

Rare Earth pcu Metal–Organic Framework Platform Based on RE 4 (μ 3 -OH) 4 (COO) 6 2+ Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths

Auteurs : Tian-Yi Luo [États-Unis] ; Chong Liu [États-Unis] ; Svetlana V. Eliseeva [France] ; Patrick F. Muldoon [États-Unis] ; Stéphane Petoud [France] ; Nathaniel L. Rosi [États-Unis]

Source :

Journal of the American Chemical Society [ 0002-7863 ] ; 2017-06-27.

RBID : Hal:hal-01618623

Abstract

The Td point group symmetry of rare earth (RE3+) metal clusters RE4(mu3-OH)4(COO)62+ makes them attractive building blocks for creating metal-organic frameworks (MOFs) with controllable topologies. Herein, we describe the design and synthesis of a series of isoreticular MOFs featuring pcu topology [MOF-1114(RE) and MOF-1115(RE)] with variable rare earth metal ions (RE3+ = Y3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+) and linear amino-functionalized dicarboxylate linkers of different lengths. In total, we report 22 MOFs that vary in both composition and structure yet share the same RE4(mu3-OH)4 cluster motif. We demonstrate that these pcu MOFs are cationic and that anion exchange can be used to affect the MOF properties. We also investigate the luminescence properties of a representative member of this MOF series [MOF-1114(Yb)] that exhibits near-infrared emission. We show that the excitation energy for Yb3+ sensitization can be carefully adjusted to lower energy via covalent postsynthetic modification at the amino group sites within the MOF.

Url:

https://hal.archives-ouvertes.fr/hal-01618623

DOI: 10.1021/jacs.7b04532

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Hal, to step Corpus: 000496
to stream Hal, to step Curation: 000496
to stream Hal, to step Checkpoint: 000013
to stream Main, to step Merge: 000013
to stream Main, to step Curation: 000013

Le document en format XML

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<author><name sortKey="Rosi, Nathaniel L" sort="Rosi, Nathaniel L" uniqKey="Rosi N" first="Nathaniel L." last="Rosi">Nathaniel L. Rosi</name>
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          <desc>            <address>              <addrLine>Pittsburgh, PA 15260</addrLine>
              <country key="US"></country>
            </address>
          </desc>
          <listRelation>            <relation active="#struct-346120" type="direct"></relation>
          </listRelation>
        <tutelles><tutelle active="#struct-346120" type="direct"><org type="institution" xml:id="struct-346120" status="INCOMING">          <orgName>University of Pittsburg</orgName>
          <desc>            <address>              <country key="FR"></country>
            </address>
          </desc>
        </org>
</tutelle>
</tutelles>
</hal:affiliation>
<country>États-Unis</country>
</affiliation>
</author>
</analytic>
<idno type="DOI">10.1021/jacs.7b04532</idno>
<series><title level="j">Journal of the American Chemical Society</title>
<idno type="ISSN">0002-7863</idno>
<imprint><date type="datePub">2017-06-27</date>
</imprint>
</series>
</biblStruct>
</sourceDesc>
</fileDesc>
<profileDesc><textClass></textClass>
</profileDesc>
</teiHeader>
<front><div type="abstract" xml:lang="en">The Td point group symmetry of rare earth (RE3+) metal clusters RE4(mu3-OH)4(COO)62+ makes them attractive building blocks for creating metal-organic frameworks (MOFs) with controllable topologies. Herein, we describe the design and synthesis of a series of isoreticular MOFs featuring pcu topology [MOF-1114(RE) and MOF-1115(RE)] with variable rare earth metal ions (RE3+ = Y3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Ho3+, Er3+, Tm3+, Yb3+) and linear amino-functionalized dicarboxylate linkers of different lengths. In total, we report 22 MOFs that vary in both composition and structure yet share the same RE4(mu3-OH)4 cluster motif. We demonstrate that these pcu MOFs are cationic and that anion exchange can be used to affect the MOF properties. We also investigate the luminescence properties of a representative member of this MOF series [MOF-1114(Yb)] that exhibits near-infrared emission. We show that the excitation energy for Yb3+ sensitization can be carefully adjusted to lower energy via covalent postsynthetic modification at the amino group sites within the MOF.</div>
</front>
</TEI>
<affiliations><list><country><li>France</li>
<li>États-Unis</li>
</country>
<region><li>Centre-Val de Loire</li>
<li>Région Centre</li>
</region>
<settlement><li>Orléans</li>
</settlement>
<orgName><li>Centre Val de Loire Université</li>
<li>Université d'Orléans</li>
</orgName>
</list>
<tree><country name="États-Unis"><noRegion><name sortKey="Luo, Tian Yi" sort="Luo, Tian Yi" uniqKey="Luo T" first="Tian-Yi" last="Luo">Tian-Yi Luo</name>
</noRegion>
<name sortKey="Liu, Chong" sort="Liu, Chong" uniqKey="Liu C" first="Chong" last="Liu">Chong Liu</name>
<name sortKey="Muldoon, Patrick F" sort="Muldoon, Patrick F" uniqKey="Muldoon P" first="Patrick F." last="Muldoon">Patrick F. Muldoon</name>
<name sortKey="Rosi, Nathaniel L" sort="Rosi, Nathaniel L" uniqKey="Rosi N" first="Nathaniel L." last="Rosi">Nathaniel L. Rosi</name>
</country>
<country name="France"><region name="Région Centre"><name sortKey="Eliseeva, Svetlana V" sort="Eliseeva, Svetlana V" uniqKey="Eliseeva S" first="Svetlana V." last="Eliseeva">Svetlana V. Eliseeva</name>
</region>
<name sortKey="Petoud, Stephane" sort="Petoud, Stephane" uniqKey="Petoud S" first="Stéphane" last="Petoud">Stéphane Petoud</name>
</country>
</tree>
</affiliations>
</record>

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Rare Earth pcu Metal–Organic Framework Platform Based on RE 4 (μ 3 -OH) 4 (COO) 6 2+ Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths

Rare Earth pcu Metal–Organic Framework Platform Based on RE 4 (μ 3 -OH) 4 (COO) 6 2+ Clusters: Rational Design, Directed Synthesis, and Deliberate Tuning of Excitation Wavelengths

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